In the other Nations League Group A3 match, it's goalless between European champions Italy and Hungary in Cesena.
Hungary beat England 1-0 at the weekend and had a chance when they were awarded a free-kick right on the edge of the penalty area but Dominik Szoboszlai, who scored against Gareth Southgate's side, could only hit it into the wall.
Post update
Germany 0-0 England
Muller-Rice in action.
I want to see them battling in the corner.
Post update
Germany 0-0 England
Rob Green
Former England goalkeeper on BBC Radio 5 Live
How long can they keep this up for? Everyone is sprinting, they know how dangerous it is to lose that ball.
Get Involved
#BBCFootball
Paul: If we win this our England fans will be hyping us up. If we lose or play poorly those same hypocrites will then be saying it’s only the nations league. I want to see a good performance and win. Not the usual cautious style Southgate usually serves up as manager.
Post update
Germany 0-0 England
England looked leggy against Hungary on Saturday, they've just been second best this evening.
Germany haven't been able to capitalise on a good start with a goal though.
Not sure that made any sense for Kalvin Phillips to come back on there. He was clearly struggling and should have been off right away.
Not having a lot of luck with injuries and he will be desperately disappointed on a big night for him.
Jude Bellingham is on and the Borussia Dortmund teenager is up against some familiar opponents.
Get Involved
#BBCFootball
James Dale: Really sad to see Phillips off like that, sums up his season
Post update
Germany 0-0 England
Declan Rice living dangerously, a backpass is almost latched onto by Thomas Muller, but Jordan Pickford is sharply off his line to clear up.
Jamal Musiala then goes sliding in at the near post and almost converts, but can't quite get a toe on it.
SUBSTITUTION
Germany 0-0 England
An early entrance for Borussia Dortmund teenager Jude Bellingham, on for Kalvin Phillips.
DISALLOWED GOAL
Germany 0-0 England
Thomas Muller has the ball in the back of the net with a cute finish, clipping the ball over Jordan Pickford.
But it is ruled out as the referee had already blown the whistle to halt play, Kalvin Phillips is down again.
Post update
Germany 0-0 England
Kalvin Phillips is back on but is barely able to move.
He's not going to last long.
Post update
Germany 0-0 England
Former England youth international Jamal Musiala is a real livewire in the final third, taking the ball, pirouetting and popping it off.
He has a shot from the edge of the area which is blocked.
Post update
Germany 0-0 England
Kalvin Phillips is not moving too cleverly here and is shaking his head.
Jude Bellingham to come on in his adopted country?
Let's wait and see as England continue with 10 men.
Post update
Germany 0-0 England
A painful one for Kalvin Phillips in the middle of the park, getting the point of Nico Schlotterbeck's knee right on his thigh.
The Leeds midfielder attempts to get back onto his feet but has to sit back down again.
CLOSE!
Germany 0-0 England
It has indeed started at a break neck speed.
Now England skipper Harry Kane lets fly from the right hand side of the box but that's not troubling Manuel Neuer, grabbing it low down like Jonny Bairstow in the slips.
Post update
Germany 0-0 England
Better from England, a quick passing move releasing Raheem Sterling in the box but the Man City forward's pull back is cut out by Antonio Rudiger.
Post update
Germany 0-0 England
England haven't got going yet, they've not managed to string two passes together. It brings the usually mild-mannered Gareth Southgate out of his seat.
He ain't happy.
Post update
Germany 0-0 England
Rob Green
Former England goalkeeper on BBC Radio 5 Live
This game has started at an electric pace. It has an amazing atmosphere to it.
Post update
Germany 0-0 England
Harry Kane lumps the ball long and it allows Manuel Neuer to sweep up for the first time, casually heading the ball down towards his centre-back Antonio Rudiger.
Get Involved
#BBCFootball
Luke: Odd Saka on the left and Sterling on the right. I doubt Germany will not see through the switch after 10 mins to opposite flanks.
Live Reporting
Shamoon Hafez
All times stated are UK
Post update
Italy 0-0 Hungary
In the other Nations League Group A3 match, it's goalless between European champions Italy and Hungary in Cesena.
Hungary beat England 1-0 at the weekend and had a chance when they were awarded a free-kick right on the edge of the penalty area but Dominik Szoboszlai, who scored against Gareth Southgate's side, could only hit it into the wall.
Post update
Germany 0-0 England
Muller-Rice in action.
I want to see them battling in the corner.
Post update
Germany 0-0 England
Rob Green
Former England goalkeeper on BBC Radio 5 Live
How long can they keep this up for? Everyone is sprinting, they know how dangerous it is to lose that ball.
Get Involved
#BBCFootball
Paul: If we win this our England fans will be hyping us up. If we lose or play poorly those same hypocrites will then be saying it’s only the nations league. I want to see a good performance and win. Not the usual cautious style Southgate usually serves up as manager.
Post update
Germany 0-0 England
England looked leggy against Hungary on Saturday, they've just been second best this evening.
Germany haven't been able to capitalise on a good start with a goal though.
Big blow for Phillips
Germany 0-0 England
Phil McNulty
BBC Sport chief football writer in Munich
Not sure that made any sense for Kalvin Phillips to come back on there. He was clearly struggling and should have been off right away.
Not having a lot of luck with injuries and he will be desperately disappointed on a big night for him.
Jude Bellingham is on and the Borussia Dortmund teenager is up against some familiar opponents.
Get Involved
#BBCFootball
James Dale: Really sad to see Phillips off like that, sums up his season
Post update
Germany 0-0 England
Declan Rice living dangerously, a backpass is almost latched onto by Thomas Muller, but Jordan Pickford is sharply off his line to clear up.
Jamal Musiala then goes sliding in at the near post and almost converts, but can't quite get a toe on it.
SUBSTITUTION
Germany 0-0 England
An early entrance for Borussia Dortmund teenager Jude Bellingham, on for Kalvin Phillips.
DISALLOWED GOAL
Germany 0-0 England
Thomas Muller has the ball in the back of the net with a cute finish, clipping the ball over Jordan Pickford.
But it is ruled out as the referee had already blown the whistle to halt play, Kalvin Phillips is down again.
Post update
Germany 0-0 England
Kalvin Phillips is back on but is barely able to move.
He's not going to last long.
Post update
Germany 0-0 England
Former England youth international Jamal Musiala is a real livewire in the final third, taking the ball, pirouetting and popping it off.
He has a shot from the edge of the area which is blocked.
Post update
Germany 0-0 England
Kalvin Phillips is not moving too cleverly here and is shaking his head.
Jude Bellingham to come on in his adopted country?
Let's wait and see as England continue with 10 men.
Post update
Germany 0-0 England
A painful one for Kalvin Phillips in the middle of the park, getting the point of Nico Schlotterbeck's knee right on his thigh.
The Leeds midfielder attempts to get back onto his feet but has to sit back down again.
CLOSE!
Germany 0-0 England
It has indeed started at a break neck speed.
Now England skipper Harry Kane lets fly from the right hand side of the box but that's not troubling Manuel Neuer, grabbing it low down like Jonny Bairstow in the slips.
Post update
Germany 0-0 England
Better from England, a quick passing move releasing Raheem Sterling in the box but the Man City forward's pull back is cut out by Antonio Rudiger.
Post update
Germany 0-0 England
England haven't got going yet, they've not managed to string two passes together. It brings the usually mild-mannered Gareth Southgate out of his seat.
He ain't happy.
Post update
Germany 0-0 England
Rob Green
Former England goalkeeper on BBC Radio 5 Live
This game has started at an electric pace. It has an amazing atmosphere to it.
Post update
Germany 0-0 England
Harry Kane lumps the ball long and it allows Manuel Neuer to sweep up for the first time, casually heading the ball down towards his centre-back Antonio Rudiger.
Get Involved
#BBCFootball
Luke: Odd Saka on the left and Sterling on the right. I doubt Germany will not see through the switch after 10 mins to opposite flanks.