Postpublished at 19:57 British Summer Time 28 June 2014
Kevin Kilbane
BBC Radio 5 live
"Willian was in tears. His head was on the floor after his penalty miss but Fred has just gone on to pick him up. What a moment for Brazil."
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Brazil through after penalty shootout
Brazil face Colombia or Uruguay in quarters
Game played in Belo Horizonte
Andy Cryer
Kevin Kilbane
BBC Radio 5 live
"Willian was in tears. His head was on the floor after his penalty miss but Fred has just gone on to pick him up. What a moment for Brazil."
Joy unconfined in Belo Horizonte - the hosts are through to the quarter-finals, where they will meet either Colombia or Uruguay.
Despair for Chile as Jara's penalty strikes the post. Brazil are through.
Neymar's stuttering run up ends with a calm finish into the net with Claudio Bravo diving the wrong way.
How is that for nerves? Marcelo Diaz slots the ball calmly down the middle.
Hulk's penalty is straight down the middle but saved by Bravo's legs. Brazil fans in despair.
Have a bit of that. A brilliant strike into the top corner.
Claudio Bravo gets a hand to Marcelo's penalty but it is not enough as the ball goes into the top corner.
The Brazil fans go wild as Cesar gets down low to parry Sanchez's penalty away.
A horrible penalty as Willian rolls the ball wide of the target.
Pinilla's penalty is straight at Julio Cesar. Easy save.
The perfect penalty. Keeper goes the wrong way.
So here we go. A penalty shootout for a place in the World Cup quarter-finals. Luis Gustavo is on his knees praying.
Brazil's David Luiz strides forward to take the first kick.
BBC Radio 5 live
South American football expert Tim Vickery: "What a moment for Julio Cesar. He made a mistake four years ago in the quarter finals against Holland. He has lived with that mistake ever since. The cameras in Brazil are focusing on him because they realise he has the chance to be the hero here and redeem himself for the mistake he made four years ago."
David Ornstein
BBC Sport in Belo Horizonte
"The hopes of an entire nation come down to a set of penalty kicks. The tension and nervousness around Estadio Mineiro is quite astonishing. The Chile fans are singing and dancing like the have nothing to lose, but defeat now would be incredibly painful for their players. Brazil goalkeeper Julio Cesar can't get in the QPR team but he is about to experience the biggest moment of his career."
Both teams are in their individual huddles. They have given everything, but they need a little bit more yet......
No one deserves to lose this but there will be a hero and there will be a villain. This is where you show your bottle.
Dan Walker
BBC Sport
"Potential headlines: Howard's Way, Neymarching On, Red Hot Chile Tekkers, Thriller From Pinilla, Willian The Conqueror, Dirty Sanchez."
Of the 204 penalties taken in World Cup shootouts, 19 have either hit the woodwork or missed the goal altogether.
Goalkeepers have saved 41 penalties in shootouts - 20.1% of the total of 204 attempts.
Read more on World Cup penalty shootouts in our IWonder guide.
Former England striker Michael Owen on Twitter:, external Chile win this on pens.
Kevin Kilbane
BBC Radio 5 live
"I have been there [for Republic of Ireland v Spain in 2002]. At this stage of the competition it is not nice. I stood up and missed my penalty. It was a big moment for me in my career. If you miss, it goes against you for the rest of your career and you think about it so much."