Huge chance for Barcelona. Neymar beats his man far too easily inside the area before teeing up Lionel Messi who fires straight at the keeper. Valencia should be 2-0 down yet, somehow, are still on level terms.

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Patient probing from Barca who are bossing this. They're enjoying lots of possession and it seems only a matter of time before they take the lead. Neymar is causing all sorts of problems 

Nevillution? I like it...

A late challenge by Javier Mascherano on Valencia's Santi Mina has Phil Neville leaping out of his seat in the dug out. Yellow card for the Barca defender. 

Valencia are unbeaten at home this season in La Liga but they will do well to keep that record judging by this shaky start. Jose Luis Gaya makes a last ditch tackle to stop Lionel Messi. 

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Here he is...Gary Neville looks on as Valencia are forced on the back-foot by Barcelona. Penny for his thoughts...

Valencia are so lucky to be on level terms. Neymar was clean through and you would have put your mortgage on him to find the net but La Liga's leading scorer blazed over.

Barcelona already lookingto land an early blow. Great trickery by Neymar who whips in a cross and Lionel Messi fires over on the volley. Moments later Neymar misses another great chance. Valencia's defence is already wobbling in these early stages.

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Whistles every time a yellow shirt touches the ball. This is the Mestalla at its best. Intimidating, atmospheric and loud. Very loud. Steady start by Valencia.

Barcelona are wearing yellow shirts and they get us under way. A new era for Valencia is about to begin.

Here come the teams. There isn't a spare seat in the Mestalla. It's a 55,000 sell-out and Gary Neville is occupying one of those seats. He'll be impressed with the atmosphere. It's rocking.

With Gary Neville officially taking charge on Sunday, it's left to Phil Neville and interim head coach Voro to take charge of Valencia tonight.

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Real Madrid briefly moved above Atletico Madrid into second spot earlier with a comfortable 4-1 win over Getafe, Karim Benzema scoring twice. However, Atletico's 2-0 win away to Granada in a 17:15 GMT kick-off has moved them back above Real and to within one point of leaders Barcelona, Diego Godin and Antoine Griezmann with the goals.

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As well as action from Valencia, we'll be bringing you score updates from Inter Milan's game with Genoa. Victory for Roberto Mancini's side will send them back to the top of Serie A.

Will Gary Neville sink or swim in Spain?

Will Gary Neville sink or swim in Spain - and why? Has he bitten off more than he can chew? Or is this the start of a fine managerial career? Tweet #bbceurofooty, external

Valencia's starting line-up includes Francisco Alcacer, who has scored six La Liga goals this season.

Valencia XI: Domenech, Vezo, Santos, Abdennour, Gaya, Parejo, Barbosa, Perez, Mina, Alcacer, De Paul.

Barcelona have wheeled out their big guns for the Mestalla. Thirty of their 33 La Liga goals this season have come from Neymar, Luis Suarez and Lionel Messi - and all three start.

Barcelona XI: Bravo, Alves, Pique, Mascherano, Alba, Busquets, Rakitic, Iniesta, Messi, Suarez, Neymar.